Volume 3 covers carbon-to-carbon single bond forming reactions involving u003ciu003espu003c/iu003eu003cSUPu003e3u003c/SUPu003e, u003ciu003espu003c/iu003eu003cSUPu003e2u003c/SUPu003e and u003ciu003espu003c/iu003e carbon centers, but only those which do not involve additions to C-X u0026pgr;-bonds. The volume first compares and contrasts the alkylation reactions of all types of u003ciu003espu003c/iu003eu003cSUPu003e3u003c/SUPu003e carbon nucleophiles and also covers vinyl and alkynyl carbanions. Following on from Volume 2, a separate section covers Friedel-Crafts alkylation reactions, which is complemented by discussions of polyene cyclizations and electrophilic transannular cyclizations in synthesis. Coupling reactions leading to u0026agr;-bond formation, and involving all types of combinations ofu003ciu003espu003c/iu003eu003cSUPu003e3u003c/SUPu003e, u003ciu003espu003c/iu003eu003cSUPu003e2u003c/SUPu003e and u003ciu003espu003c/iu003e carbon centers are next covered, including those reactions based on pinacol, acyloin and phenol oxidative coupling reactions, and also the Kolbe reaction. Rearrangement reactions, leading to carbon-to-carbon u0026agr;-bond formation, are often used in a clever manner in synthesis. The volume includes all those rearrangement reactions based on intermediate carbonium ions and carbanions, and also includes the benzil-benzilic acid and the Wolff rearrangements. The volume closes with coverage of carbonylation reactions, and the use of carbene insertion reactions into the C-H bond in synthesis.
Carbon-Carbon ?-Bond Formation
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